[Cu(HF2)2(pyz)]n: A rectangular antiferromagnetic lattice with a spin exchange path made up of two different FHF- bridges

The two-dimensional antiferromagnet [Cu(HF2)2(pyz)] n (pyz=pyrazine) has a rectangular lattice (see picture) displaying two types of FHF- bridging modes. The spin exchange through Cu-(FHF)2-Cu is about 90% stronger than through Cu-pyz-Cu, and the 1,1-coordinated FHF-, which is close in nature to F -...

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Bibliographic Details
Main Authors: Manson, J, Warter, M, Schlueter, J, Lancaster, T, Steele, A, Blundell, S, Pratt, F, Singleton, J, McDonald, R, Lee, C, Whangbo, M, Plonczak, A
Format: Journal article
Language:English
Published: 2011