CHANNEL ELECTRODE VOLTAMMETRY AND ELECTRODIMERIZATION PROCESSES - THE ELECTROOXIDATION OF TRIS(DITHIOCARBAMATO)COBALT(III) COMPLEXES
Channel electrode waveshape analysis is used to demonstrate that the electro-oxidation of the tris(dithiocarbamato)cobalt(III) complexes, Co(R2dtc)3, where R = Me and Et, at platinum electrodes in acetonitrile solution proceeds via an EC2 (dimerization) mechanism in which the one-electron oxidation...
Main Authors: | , , , , , |
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Format: | Journal article |
Language: | English |
Published: |
1995
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