CHANNEL ELECTRODE VOLTAMMETRY AND ELECTRODIMERIZATION PROCESSES - THE ELECTROOXIDATION OF TRIS(DITHIOCARBAMATO)COBALT(III) COMPLEXES
Channel electrode waveshape analysis is used to demonstrate that the electro-oxidation of the tris(dithiocarbamato)cobalt(III) complexes, Co(R2dtc)3, where R = Me and Et, at platinum electrodes in acetonitrile solution proceeds via an EC2 (dimerization) mechanism in which the one-electron oxidation...
| Main Authors: | , , , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
1995
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| _version_ | 1826287556957831168 |
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| author | Compton, R Eklund, J Nei, L Bond, A Colton, R Mah, Y |
| author_facet | Compton, R Eklund, J Nei, L Bond, A Colton, R Mah, Y |
| author_sort | Compton, R |
| collection | OXFORD |
| description | Channel electrode waveshape analysis is used to demonstrate that the electro-oxidation of the tris(dithiocarbamato)cobalt(III) complexes, Co(R2dtc)3, where R = Me and Et, at platinum electrodes in acetonitrile solution proceeds via an EC2 (dimerization) mechanism in which the one-electron oxidation product, Co(R2dtc)+3, undergoes irreversible dimerization resulting in the formation of Co2(R2dtc)+5. Both the shift in half-wave potential and in the voltammetric shape as revealed by Tafel analysis are used to derive kinetic parameters for the dimerization reaction, which are found to be in excellent agreement with independently determined values. © 1995. |
| first_indexed | 2024-03-07T02:00:28Z |
| format | Journal article |
| id | oxford-uuid:9d33af8d-753a-454b-8a98-6086f90a15fc |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:00:28Z |
| publishDate | 1995 |
| record_format | dspace |
| spelling | oxford-uuid:9d33af8d-753a-454b-8a98-6086f90a15fc2022-03-27T00:41:11ZCHANNEL ELECTRODE VOLTAMMETRY AND ELECTRODIMERIZATION PROCESSES - THE ELECTROOXIDATION OF TRIS(DITHIOCARBAMATO)COBALT(III) COMPLEXESJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9d33af8d-753a-454b-8a98-6086f90a15fcEnglishSymplectic Elements at Oxford1995Compton, REklund, JNei, LBond, AColton, RMah, YChannel electrode waveshape analysis is used to demonstrate that the electro-oxidation of the tris(dithiocarbamato)cobalt(III) complexes, Co(R2dtc)3, where R = Me and Et, at platinum electrodes in acetonitrile solution proceeds via an EC2 (dimerization) mechanism in which the one-electron oxidation product, Co(R2dtc)+3, undergoes irreversible dimerization resulting in the formation of Co2(R2dtc)+5. Both the shift in half-wave potential and in the voltammetric shape as revealed by Tafel analysis are used to derive kinetic parameters for the dimerization reaction, which are found to be in excellent agreement with independently determined values. © 1995. |
| spellingShingle | Compton, R Eklund, J Nei, L Bond, A Colton, R Mah, Y CHANNEL ELECTRODE VOLTAMMETRY AND ELECTRODIMERIZATION PROCESSES - THE ELECTROOXIDATION OF TRIS(DITHIOCARBAMATO)COBALT(III) COMPLEXES |
| title | CHANNEL ELECTRODE VOLTAMMETRY AND ELECTRODIMERIZATION PROCESSES - THE ELECTROOXIDATION OF TRIS(DITHIOCARBAMATO)COBALT(III) COMPLEXES |
| title_full | CHANNEL ELECTRODE VOLTAMMETRY AND ELECTRODIMERIZATION PROCESSES - THE ELECTROOXIDATION OF TRIS(DITHIOCARBAMATO)COBALT(III) COMPLEXES |
| title_fullStr | CHANNEL ELECTRODE VOLTAMMETRY AND ELECTRODIMERIZATION PROCESSES - THE ELECTROOXIDATION OF TRIS(DITHIOCARBAMATO)COBALT(III) COMPLEXES |
| title_full_unstemmed | CHANNEL ELECTRODE VOLTAMMETRY AND ELECTRODIMERIZATION PROCESSES - THE ELECTROOXIDATION OF TRIS(DITHIOCARBAMATO)COBALT(III) COMPLEXES |
| title_short | CHANNEL ELECTRODE VOLTAMMETRY AND ELECTRODIMERIZATION PROCESSES - THE ELECTROOXIDATION OF TRIS(DITHIOCARBAMATO)COBALT(III) COMPLEXES |
| title_sort | channel electrode voltammetry and electrodimerization processes the electrooxidation of tris dithiocarbamato cobalt iii complexes |
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