Wavepacket splitting and two-pathway deactivation in the photoexcited visual pigment isorhodopsin.

Isorhodopsin is the visual pigment analogue of rhodopsin. It shares the same opsin environment but it embeds 9-cis retinal instead of 11-cis. Its photoisomerization is three times slower and less effective. The mechanistic rationale behind this observation is revealed by combining high-level quantum...

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Bibliographic Details
Main Authors: Polli, D, Weingart, O, Brida, D, Poli, E, Maiuri, M, Spillane, K, Bottoni, A, Kukura, P, Mathies, R, Cerullo, G, Garavelli, M
Format: Journal article
Language:English
Published: 2014