Controlling concatenation in germanium(I) chemistry through hemilability

We present a novel approach for constructing chains of Group 14 metal atoms linked by unsupported metal–metal bonds that exploits hemilabile ligands to generate unsaturated metal sites. The formation/nature of catenated species (oligo-dimetallynes) can be controlled by the use of (acidic/basic) “pro...

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Bibliographic Details
Main Authors: Caise, A, Griffin, LP, Heilmann, A, McManus, C, Campos, J, Aldridge, S
Format: Journal article
Language:English
Published: Wiley 2021