Heptaphosphide cluster anions bearing group 14 element amide functionalities.
Reactions of the protonated heptaphosphide dianion, [HP7](2-), with one equivalent of E[N(SiMe3)2]2 (E = Ge, Sn, Pb) give rise to novel derivatized cluster anions [P7EN(SiMe3)2](2-) (E = Ge (1), Sn (2) and Pb (3)). All three species were characterized by multi-element solution-phase NMR spectroscopy...
| Main Authors: | , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
Royal Society of Chemistry
2016
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