A comparison of the Butler-Volmer and asymmetric Marcus-Hush models of electrode kinetics at the channel electrode

We report a theoretical study of steady-state voltammetry at the channel electrode comparing the Butler-Volmer and Marcus-Hush (both symmetric and asymmetric) models of electrode kinetics. The latter model is shown, for small values of both reorganisation energy and standard rate constant, to exhibi...

Full description

Bibliographic Details
Main Authors: Henstridge, M, Rees, N, Compton, R
Format: Journal article
Language:English
Published: 2012