A comparison of the Butler-Volmer and asymmetric Marcus-Hush models of electrode kinetics at the channel electrode
We report a theoretical study of steady-state voltammetry at the channel electrode comparing the Butler-Volmer and Marcus-Hush (both symmetric and asymmetric) models of electrode kinetics. The latter model is shown, for small values of both reorganisation energy and standard rate constant, to exhibi...
| Autores principales: | , , |
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| Formato: | Journal article |
| Lenguaje: | English |
| Publicado: |
2012
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