Enantioconvergent nucleophilic substitution via synergistic phase-transfer catalysis

Enantioconvergent nucleophilic substitution via synergistic phase-transfer catalysis

Catalytic enantioconvergent nucleophilic substitution reactions of alkyl halides are highly valuable transformations, but they are notoriously difficult to implement. Specifically, nucleophilic fluorination is a renowned challenge, especially when inexpensive alkali metal fluorides are used as fluor...

पूर्ण विवरण

ग्रंथसूची विवरण
मुख्य लेखकों:	Dooley, C, Ibba, F, Botlik, BB, Palladino, C, Goult, CA, Gao, Y, Lister, A, Paton, RS, Lloyd-Jones, GC, Gouverneur, V
स्वरूप:	Journal article
भाषा:	English
प्रकाशित:	Nature Research 2025

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Transition metal catalysis and nucleophilic fluorination.
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Nucleophilic substitution/
द्वारा: 235144 Barlin, G. B.
प्रकाशित: (1975)

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प्रकाशित: (2017-06-01)

Nucleophilic aliphatic substitution/
द्वारा: 224038 Stevens, I. D. R.
प्रकाशित: (1972)

Nucleophilic aliphatic substitution/
द्वारा: 224038 Stevens, I. D. R.
प्रकाशित: (1973)

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