A combined experimental and computational study of fluxional processes in sigma amine-borane complexes of rhodium and iridium.
A combined experimental and computational study on the fluxional processes involving the M-H and B-H positions in the sigma amine-borane complexes [M(PR3)2(H)2(η(2)-H3B·NMe3)][BAr(F)4] (M = Rh, Ir; R = Cy for experiment; R = Me, Cy for computation; Ar(F) = 3,5-(CF3)2C6H3) is reported. The processes...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2014
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