A combined experimental and computational study of fluxional processes in sigma amine-borane complexes of rhodium and iridium.

A combined experimental and computational study on the fluxional processes involving the M-H and B-H positions in the sigma amine-borane complexes [M(PR3)2(H)2(η(2)-H3B·NMe3)][BAr(F)4] (M = Rh, Ir; R = Cy for experiment; R = Me, Cy for computation; Ar(F) = 3,5-(CF3)2C6H3) is reported. The processes...

সম্পূর্ণ বিবরণ

গ্রন্থ-পঞ্জীর বিবরন
প্রধান লেখক: Algarra, A, Sewell, L, Johnson, H, Macgregor, SA, Weller, A
বিন্যাস: Journal article
ভাষা:English
প্রকাশিত: Royal Society of Chemistry 2014