A monomeric organolithium compound containing a free pyramidal carbanion in solution and in the solid state.
A suitable bridle, created by intramolecular chelation of the Li cation, and lack of π delocalization, yielded the first monomeric lithium organyl compound containing an unassociated tetrahedral carbanionic center (see picture). The zwitterionic structure found in the solid state is preserved in sol...
| Main Authors: | , , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado: |
2004
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