Diastereoselective synthesis of P-stereogenic heterocycles via enyne ring-closing metathesis.
A range of P-containing ene-diynes suitable for desymmetrization was prepared via a two-step process starting from phosphorus oxychloride. In the presence of the Hoveyda-Grubbs II catalyst, these substrates underwent diastereoselective enyne ring-closing metathesis leading to various synthetically u...
Hoofdauteurs: | , , |
---|---|
Formaat: | Journal article |
Taal: | English |
Gepubliceerd in: |
2010
|