Quantifying the apparent 'Catalytic' effect of porous electrode surfaces

Quantifying the apparent 'Catalytic' effect of porous electrode surfaces

The voltammetry of porous electroactive surfaces is investigated by simulation. The surface is modelled as a solid block penetrated by a regularly distributed array of cylindrical pores. The effect of the voltage scan rate and the geometry (in terms of pore depth, radius, and inter-pore separation)...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид:	Ward, K, Compton, R
Формат:	Journal article
Хэл сонгох:	English
Хэвлэсэн:	Elsevier 2014

Ижил төстэй зүйлс

Nanoparticle modified electrodes can show an apparent increase in electrode kinetics due solely to altered surface geometry: The effective electrochemical rate constant for non-flat and non-uniform electrode surfaces
-н: Ward, K, зэрэг
Хэвлэсэн: (2013)

THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC (CATALYTIC) MECHANISM
-н: Compton, R, зэрэг
Хэвлэсэн: (1991)

Exploring the origins of the apparent "electrocatalysis" observed at C(60) film-modified electrodes
-н: Xiao, L, зэрэг
Хэвлэсэн: (2009)

Voltammetry using multiple cycles: Porous electrodes
-н: Chan, H, зэрэг
Хэвлэсэн: (2017)

Regular arrays of microdisc electrodes: simulation quantifies the fraction of 'dead' electrodes.
-н: Ordeig, O, зэрэг
Хэвлэсэн: (2006)

Cyclic voltammetry on electrode surfaces covered with porous layers: An analysis of electron transfer kinetics at single-walled carbon nanotube modified electrodes
-н: Streeter, I, зэрэг
Хэвлэсэн: (2008)

Voltammetry at porous electrodes: A theoretical study
-н: Barnes, E, зэрэг
Хэвлэсэн: (2014)

Amperometric detection of glucose using self-catalytic carbon paste electrodes.
-н: Evans, R, зэрэг
Хэвлэсэн: (2004)

Voltammetry at electrodes decorated with an insulating porous film: Understanding the effects of adsorption
-н: Chan, HTH, зэрэг
Хэвлэсэн: (2017)

Catalytic mechanism in cyclic voltammetry at disc electrodes: an analytical solution.
-н: Molina, A, зэрэг
Хэвлэсэн: (2011)

Advancing from Rules of Thumb: Quantifying the Effects of Small Density Changes in Mass Transport to Electrodes. Understanding Natural Convection.
-н: Ngamchuea, K, зэрэг
Хэвлэсэн: (2015)

Apparent Parameters of Enzymatic Plate-Gap Electrode
-н: I. Kaunietis, зэрэг
Хэвлэсэн: (2005-07-01)

Mass transport to and within porous electrodes. Linear sweep voltammetry and the effects of pore size: The prediction of double peaks for a single electrode process
-н: Henstridge, M, зэрэг
Хэвлэсэн: (2012)

A self-catalytic carbon paste electrode for the detection of vitamin B12.
-н: Tomcik, P, зэрэг
Хэвлэсэн: (2004)

Analytical theory of the catalytic mechanism in square wave voltammetry at disc electrodes.
-н: Molina, A, зэрэг
Хэвлэсэн: (2011)

ROTATING-DISK ELECTRODE VOLTAMMETRY - THE CATALYTIC MECHANISM (EC) AND ITS NUANCES
-н: Compton, R, зэрэг
Хэвлэсэн: (1988)

Catalytic and Inhibitory Kinetic Behavior of Horseradish Peroxidase on the Electrode Surface
-н: Titi Wang, зэрэг
Хэвлэсэн: (2012-10-01)

Quantifying single-carbon nanotube-electrode contact via the nanoimpact method
-н: Li, X, зэрэг
Хэвлэсэн: (2017)

In Situ Detection of Particle Aggregation on Electrode Surfaces.
-н: Ngamchuea, K, зэрэг
Хэвлэсэн: (2015)

The transient and stationary behaviour of first-order catalytic mechanisms at disc and hemisphere electrodes
-н: Molina, A, зэрэг
Хэвлэсэн: (2011)

Electrode processes at the surfaces of sonotrodes
-н: Compton, R, зэрэг
Хэвлэсэн: (1996)

Shielding of a Microdisc Electrode Surrounded by an Adsorbing Surface
-н: Eloul, S, зэрэг
Хэвлэсэн: (2014)

Pore geometry control of apparent wetting in porous media
-н: Harris Sajjad Rabbani, зэрэг
Хэвлэсэн: (2018-10-01)

Pore geometry control of apparent wetting in porous media
-н: Rabbani, Harris Sajjad, зэрэг
Хэвлэсэн: (2022)

Pore geometry control of apparent wetting in porous media
-н: Rabbani, Harris Sajjad, зэрэг
Хэвлэсэн: (2021)

How can electrode surface modification benefit electroanalysis?
-н: Tanner, E, зэрэг
Хэвлэсэн: (2018)

Chemical instability promotes apparent electrochemical irreversibility: Studies on the electrode kinetics of the one electron reduction of the 2,6-diphenylpyrylium cation in acetonitrile solution
-н: Streeter, I, зэрэг
Хэвлэсэн: (2007)

Nanomaterial modified electrodes: evaluating oxygen reduction catalysts.
-н: Gara, M, зэрэг
Хэвлэсэн: (2013)

THE ELECTROCHEMISTRY OF [PTH(PET3)3]+ - INVERTED AND AMPLIFIED CYCLIC VOLTAMMETRIC WAVES AND CATALYTIC HYDROGEN-PRODUCTION AT A MERCURY-ELECTRODE
-н: Compton, R, зэрэг
Хэвлэсэн: (1986)

A non-invasive method to directly quantify surface heterogeneity of porous materials
-н: Wei-Shan Chiang, зэрэг
Хэвлэсэн: (2018-02-01)

INVERTED AND AMPLIFIED WAVES IN CYCLIC VOLTAMMOGRAMS OF [PTH(PET3)3]+ - CATALYTIC PRODUCTION OF HYDROGEN AT A MERCURY-ELECTRODE
-н: Fisher, J, зэрэг
Хэвлэсэн: (1983)

The Marcus-Hush model of electrode kinetics at a single nanoparticle
-н: Henstridge, M, зэрэг
Хэвлэсэн: (2014)

Electrochemical processes mediated via adsorbed Enzymes: Flat and porous electrodes Compared. Understanding Nano-confinement
-н: Le, H, зэрэг
Хэвлэсэн: (2021)

Using the Wild Bootstrap to Quantify Uncertainty in Mean Apparent Propagator MRI
-н: Xuan Gu, зэрэг
Хэвлэсэн: (2019-06-01)

Ultrasonic effects on the electro-reduction of oxygen at a glassy carbon anthraquinone-modified electrode. The Koutecky-Levich equation applied to insonated electro-catalytic reactions
-н: Salimi, A, зэрэг
Хэвлэсэн: (2003)

Porous catalytic membranes for CO₂ conversion
-н: Guo, Yi, зэрэг
Хэвлэсэн: (2022)

Singlet oxygen and the origin of oxygen functionalities on the surface of carbon electrodes
-н: Chaisiwamongkhol, K, зэрэг
Хэвлэсэн: (2018)

Multiphase Porous Electrode Theory
-н: Smith, Raymond B, зэрэг
Хэвлэсэн: (2021)

Multiphase Porous Electrode Theory
-н: Smith, Raymond Barrett, зэрэг
Хэвлэсэн: (2022)

Homogeneous and heterogeneous catalytic redox processes: Solution and solid state voltammetry of lead complexes at carbon electrodes
-н: Marken, F, зэрэг
Хэвлэсэн: (1997)