6C-butylglucoses from glucuronolactone: Suppression of silyl migration during borohydride reduction of lactols by cerium (III) chloride: Inhibition of phosphoglucomutase

The synthesis of the epimeric 6C-butylglucoses from D-glucuronolactone is reported. The sodium borohydride reduction of two fully protected lactols is highly stereoselective but is accompanied by migration of a silyl protecting group; in the presence of cerium(III) chloride, there is little change i...

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Detalhes bibliográficos
Principais autores: Masaguer, C, Bleriot, Y, Charlwood, J, Winchester, BG, Fleet, G
Formato: Journal article
Idioma:English
Publicado em: 1997