Concerning directed oxidation and transacylation during a general approach to hydroxylated lactams
A variant of Knight's route to d-mannolactam, exploring the stereoselectivity of directed oxidation conditions, reveals a tendency for hydroxylated N-tosyl lactams to rearrange to γ-lactones. An attempted directed dihydroxylation in this series is shown to result in unexpectedly high anti-selec...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2009
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