Early Transition Metal Permethylpentalene Complexes for the Polymerization of Ethylene

A series of group 4 permethylpentalene-cyclopentadiene mixed sandwich complexes have been synthesized including the mono- and bis-cyclopentadienyl derivatives Pn*MCp2-xClx (Pn* = η8-C8Me6, M = Ti, Zr, Hf, x = 0, 1) and the monopentamethylcyclopentadienyl species Pn*MCpCl (Pn* = η8-C8Me6, M = Ti, Zr,...

Full description

Bibliographic Details
Main Authors: Chadwick, F, Cooper, RT, Ashley, A, Buffet, J, O'Hare, D
Format: Journal article
Language:English
Published: American Chemical Society 2014