Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine.

Reactions of the 2-phosphaethynolate anion (PCO(-), 1) with ammonium salts quantitatively yielded phosphinecarboxamide (PH2C(O)NH2, 2). The molecular structure and chemical properties of 2 were studied by single-crystal X-ray diffraction and multielement NMR spectroscopy. This phosphorus-containing...

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Bibliographic Details
Main Authors: Jupp, A, Goicoechea, J
Format: Journal article
Language:English
Published: 2013