Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine.
Reactions of the 2-phosphaethynolate anion (PCO(-), 1) with ammonium salts quantitatively yielded phosphinecarboxamide (PH2C(O)NH2, 2). The molecular structure and chemical properties of 2 were studied by single-crystal X-ray diffraction and multielement NMR spectroscopy. This phosphorus-containing...
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| Format: | Journal article |
| Language: | English |
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2013
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| _version_ | 1797086791694548992 |
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| author | Jupp, A Goicoechea, J |
| author_facet | Jupp, A Goicoechea, J |
| author_sort | Jupp, A |
| collection | OXFORD |
| description | Reactions of the 2-phosphaethynolate anion (PCO(-), 1) with ammonium salts quantitatively yielded phosphinecarboxamide (PH2C(O)NH2, 2). The molecular structure and chemical properties of 2 were studied by single-crystal X-ray diffraction and multielement NMR spectroscopy. This phosphorus-containing analogue of urea is a rare example of an air-stable primary phosphine. |
| first_indexed | 2024-03-07T02:26:59Z |
| format | Journal article |
| id | oxford-uuid:a5f07975-36f3-45a0-818c-b4046977865d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:26:59Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | oxford-uuid:a5f07975-36f3-45a0-818c-b4046977865d2022-03-27T02:43:54ZPhosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a5f07975-36f3-45a0-818c-b4046977865dEnglishSymplectic Elements at Oxford2013Jupp, AGoicoechea, JReactions of the 2-phosphaethynolate anion (PCO(-), 1) with ammonium salts quantitatively yielded phosphinecarboxamide (PH2C(O)NH2, 2). The molecular structure and chemical properties of 2 were studied by single-crystal X-ray diffraction and multielement NMR spectroscopy. This phosphorus-containing analogue of urea is a rare example of an air-stable primary phosphine. |
| spellingShingle | Jupp, A Goicoechea, J Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine. |
| title | Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine. |
| title_full | Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine. |
| title_fullStr | Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine. |
| title_full_unstemmed | Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine. |
| title_short | Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine. |
| title_sort | phosphinecarboxamide a phosphorus containing analogue of urea and stable primary phosphine |
| work_keys_str_mv | AT juppa phosphinecarboxamideaphosphoruscontaininganalogueofureaandstableprimaryphosphine AT goicoecheaj phosphinecarboxamideaphosphoruscontaininganalogueofureaandstableprimaryphosphine |