Molecular motion of endohedral fullerenes in single-walled carbon nanotubes

Rock and roll: Endohedral fullerenes Ce@C82 inserted in single-walled carbon nanotubes (SWNTs) interact by electrostatic interactions and exhibit unusual dynamic behavior. Translational oscillations and discontinuous molecular rotations are observed (by high-resolution transmission electron microsco...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: Khlobystov, A, Porfyrakis, K, Kanai, M, Britz, D, Ardavan, A, Shinohara, H, Dennis, T, Briggs, G
Формат: Journal article
Хэл сонгох:English
Хэвлэсэн: 2004
Тодорхойлолт
Тойм:Rock and roll: Endohedral fullerenes Ce@C82 inserted in single-walled carbon nanotubes (SWNTs) interact by electrostatic interactions and exhibit unusual dynamic behavior. Translational oscillations and discontinuous molecular rotations are observed (by high-resolution transmission electron microscopy) for the first time for molecular arrays inside SWNTs (see picture; blue dot=endohedral Ce atom). The fullerene rotation rate is different for isolated and aggregated nanotubes.