Syntheses, reactivity and DFT studies of group 2 and group 12 metal complexes of tris(pyrazolyl)methanides featuring "free" pyramidal carbanions.

Syntheses, reactivity and DFT studies of group 2 and group 12 metal complexes of tris(pyrazolyl)methanides featuring "free" pyramidal carbanions.

Reactions of HC(Me2pz)3 with Grignard reagents, dialkyl magnesium compounds and dimethylzinc are reported, together with a DFT study on some of the aspects of this chemistry. Reactions of HC(Me2pz)3 with MeMgX (X=Cl or Br) gave the half-sandwich zwitterionic compounds [Mg((Me)Tpmd)X] (X=Cl (2) or Br...

Bibliografski detalji
Glavni autori:	Bigmore, H, Meyer, J, Krummenacher, I, Rüegger, H, Clot, E, Mountford, P, Breher, F
Format:	Journal article
Jezik:	English
Izdano:	2008

Slični predmeti

Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methane and Zwitterionic Tris(pyrazolyl)methanide Compounds
od: Cushion, MG, i dr.
Izdano: (2010)

Syntheses, structures and electronic properties of zwitterionic iron(II) and cobalt(II) complexes featuring ambidentate tris(pyrazolyl)methanide ligands.
od: Kuzu, I, i dr.
Izdano: (2009)

A monomeric organolithium compound containing a free pyramidal carbanion in solution and in the solid state.
od: Breher, F, i dr.
Izdano: (2004)

Coordination, organometallic and related chemistry of tris(pyrazolyl)methane ligands.
od: Bigmore, H, i dr.
Izdano: (2005)

Imidotitanium Tris(pyrazolyl)hydroborates: Synthesis, Solution Dynamics, and Solid-State Structure.
od: Dunn, S, i dr.
Izdano: (1996)

Group 12 Metal Complexes of N-Heterocyclic Ditopic Carbanionic Carbenes
od: Waters, J, i dr.
Izdano: (2013)

Synthesis, Structure, and Reactivity of Molybdenum– and Tungsten–Indane Complexes with Tris(pyrazolyl)borate Ligand
od: Masumi Itazaki, i dr.
Izdano: (2024-02-01)

The crystal structure of trimethylsulfonium tris(trifluoromethylsulfonyl)methanide, C7H9F9O6S4
od: Wirthensohn Raphael, i dr.
Izdano: (2021-03-01)

Carbanion chemistry/
od: Bates, Robert B, i dr.
Izdano: (1983)

Ti=NR vs Ti-R ' Functional Group Selectivity in Titanium Imido Alkyl Cations from a DFT Perspective
od: Feliz, M, i dr.
Izdano: (2008)

Synthesis and Characterization of a Sulfonyl- and Iminophosphoryl-Functionalized Methanide and Methandiide
od: Kai-Stephan Feichtner, i dr.
Izdano: (2016-12-01)

Comprehensive carbanion chemistry/
od: Buncel, E., i dr.
Izdano: (1980)

Synthesis of metal (Iminophosphinoyl)(thiophosphinoyl) methanide and methanediide complexes
od: Guo, Jiayi
Izdano: (2012)

Agostic interactions in alkyl derivatives of sterically hindered tris(pyrazolyl)borate complexes of niobium
od: Etienne, M, i dr.
Izdano: (2009)

C-H and C-C agostic interactions in cycloalkyl tris(pyrazolyl)boratoniobium complexes
od: Jaffart, J, i dr.
Izdano: (2003)

Carbanions : Mechanistic and isotopic aspects/
od: 267888 Buncel, E.
Izdano: (1975)

An unprecedented alpha-C-C agostic interaction in a cyclopropyl tris(pyrazolyl)boratoniobium complex.
od: Jaffart, J, i dr.
Izdano: (2003)

The first group 4 metal bis(imido) and tris(imido) complexes
od: Schwarz, A, i dr.
Izdano: (2012)

Electrochemical and photophysical properties of DNA metallo-intercalators containing the ruthenium(II) tris(1-pyrazolyl)methane unit.
od: Foxon, S, i dr.
Izdano: (2007)

Tris-{Hydridotris(1-pyrazolyl)borato}lanthanide Complexes: Synthesis, Spectroscopy, Crystal Structure and Bonding Properties
od: Christos Apostolidis, i dr.
Izdano: (2021-06-01)

Alkali metal salts of ditopic carbanionic carbenes as reagents for the synthesis of novel complexes of group 12 and 14 metals.
od: Waters, J, i dr.
Izdano: (2014)

The role of an aromatic group in remote chiral induction during conjugate addition of α-sulfonylallylic carbanions to ethyl crotonate
od: Shlomo Levinger, i dr.
Izdano: (2008-09-01)

Experimental and DFT studies of cationic imido titanium alkyls: Agostic interactions and C-H bond and solvent activation reactions of isolobal analogues of group 4 metallocenium cations
od: Bolton, P, i dr.
Izdano: (2006)

Iron(II) complexes of ditopic carbanionic carbenes.
od: Musgrave, R, i dr.
Izdano: (2014)

On the reactions of tertiary carbanions with some nitroindazoles and nitrobenzotriazoles
od: Marek K. Bernard, i dr.
Izdano: (2012-07-01)

Observing and modelling energetically close alpha- and beta-carbon-hydrogen agostic interactions in an isopropyl tris(pyrazolyl)boratoniobium complex
od: Jaffart, J, i dr.
Izdano: (1998)

Tris-(2-pyridyl)-pyrazolyl Borate Zinc(II) Complexes: Synthesis, DNA/Protein Binding and In Vitro Cytotoxicity Studies
od: Manmath Narwane, i dr.
Izdano: (2021-12-01)

HYDROTRIS(PYRAZOLYL)BORATE THALLIUM(I) [TpTI(I)] CHEMISTRY SYNTHESES AND APPLICATIONS
od: Janiak, Christoph
Izdano: (1998-01-01)

Synthesis and Characterisation of Lanthanide N-Trimethylsilyl and -Mesityl Functionalised Bis(iminophosphorano)methanides and -Methanediides
od: George Marshall, i dr.
Izdano: (2013-12-01)

The Food Groups of MyPyramid
od: Glenda L. Warren
Izdano: (2009-04-01)

The Food Groups of MyPyramid
od: Glenda L. Warren
Izdano: (2009-04-01)

The Food Groups of MyPyramid
od: Glenda L. Warren
Izdano: (2009-04-01)

Solventless Synthesis of Poly(pyrazolyl)phenyl-methane Ligands and Thermal Transformation of Tris(3,5-dimethylpyrazol-1-yl)phenylmethane
od: Edith Rodríguez-Venegas, i dr.
Izdano: (2017-03-01)

New titanium imido synthons: syntheses and supramolecular structures.
od: Adams, N, i dr.
Izdano: (2005)

Synthesis, DFT studies, and reactions of scandium and yttrium dialkyl cations containing neutral fac-N-3 and fac-S-3 donor ligands
od: Tredget, C, i dr.
Izdano: (2008)

Synthesis and Characterization of Catecholato Copper(II) Complexes with Sterically Hindered Neutral and Anionic N3 Type Ligands: Tris(3,5-diisopropyl-1-pyrazolyl)methane and Hydrotris(3,5-diisopropyl-1-pyrazolyl)borate
od: Kiyoshi Fujisawa, i dr.
Izdano: (2020-05-01)

Deprotonation of group 14 metal amide complexes bearing ditopic carbanionic n-heterocyclic carbene ligands. Constitutional isomerism and dynamic behavior
od: Waters, J, i dr.
Izdano: (2017)

Crystal structure of dichlorido[tris(pyrazolyl)borate]triphenylphosphinerhenium(III), C27H25BCl2N6PRe
od: Zhang Ran, i dr.
Izdano: (2013-10-01)

Carbanionic Route to Electroactive Carbon-Centered Anion and Radical Oligomers
od: Dane, Eric L., i dr.
Izdano: (2011)

Further evidence in favour of a carbanion mechanism for glycolate oxidase
od: Hélène Pasquier, i dr.
Izdano: (2023-05-01)