Identifying the role of terahertz vibrations in metal-organic frameworks: from gate-opening phenomenon to shear-driven structural destabilization.

Identifying the role of terahertz vibrations in metal-organic frameworks: from gate-opening phenomenon to shear-driven structural destabilization.

We present an unambiguous identification of low-frequency terahertz vibrations in the archetypal imidazole-based metal-organic framework (MOF) materials: ZIF-4, ZIF-7, and ZIF-8, all of which adopt a zeolite-like nanoporous structure. Using inelastic neutron scattering and synchrotron radiation far-...

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Príomhchruthaitheoirí:	Ryder, M, Civalleri, B, Bennett, T, Henke, S, Rudić, S, Cinque, G, Fernandez-Alonso, F, Tan, J
Formáid:	Journal article
Teanga:	English
Foilsithe / Cruthaithe:	American Physical Society 2014

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