Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable.

Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable.

A series of single electron-transfer (SET) reactions on a naphthyl thioether have shown that the reductive cleavage mechanism changes at low temperatures and this selectivity is proved using an electrochemical analysis that mimics the SET reaction conditions.

Sonraí bibleagrafaíochta
Príomhchruthaitheoirí:	Paddon, C, Bhatti, F, Donohoe, T, Compton, R
Formáid:	Journal article
Teanga:	English
Foilsithe / Cruthaithe:	2006

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