Layered CeSO and LiCeSO oxide chalcogenides obtained via topotactic oxidative and reductive transformations
The chemical accessibility of the CeIV oxidation state enables redox chemistry to be performed on the naturally coinage-metal-deficient phases CeM1–xSO (M = Cu, Ag). A metastable black compound with the PbFCl structure type (space group P4/nmm: a = 3.8396(1) Å, c = 6.607(4) Å, V = 97.40(6) Å3) and a...
Main Authors: | , , , |
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Format: | Journal article |
Published: |
American Chemical Society
2019
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