Nonadiabatic interactions in the Cl + H2 reaction probed by ClH2- and ClD2- photoelectron imaging.

The degree of electronic and nuclear coupling in the Cl + H2 reaction has become a vexing problem in chemical dynamics. We report slow electron velocity-map imaging (SEVI) spectra of ClH2- and ClD2-. These spectra probe the reactant valley of the neutral reaction potential energy surface, where nona...

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Bibliographic Details
Main Authors: Garand, E, Zhou, J, Manolopoulos, D, Alexander, M, Neumark, D
Format: Journal article
Language:English
Published: 2008