Boryl substituted group 13 metallylenes: complexes with an iron carbonyl fragment.
The first examples of boryl substituted aluminylene and gallylene complexes, [(DAB)B(THF)Al{Fe(CO)3(μ-CO)}]2 and [(DAB)BGa{μ-Fe(CO)4}]2 (DAB = {(C6H3Pr(i)2-2,6)NCH}2) have been prepared by reduction of MX2(THF){B(DAB)} (M = Al or Ga, X = Cl or Br) with K2[Fe(CO)4]. Spectroscopic and crystallographic...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2016
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