Antiferromagnetism in a family of S = 1 square lattice coordination polymers NiX2(pyz)2 (X = Cl, Br, I, NCS; pyz = Pyrazine).

The crystal structures of NiX2(pyz)2 (X = Cl (1), Br (2), I (3) and NCS (4)) were determined at 298 K by synchrotron X-ray powder diffraction. All four compounds consist of two-dimensional (2D) square arrays self-assembled from octahedral NiN4X2 units that are bridged by pyz ligands. The 2D layered...

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Bibliographic Details
Main Authors:	Liu, J, Goddard, P, Singleton, J, Brambleby, J, Foronda, F, Möller, J, Kohama, Y, Ghannadzadeh, S, Ardavan, A, Blundell, S, Lancaster, T, Xiao, F, Williams, R, Pratt, F, Baker, P, Wierschem, K, Lapidus, S, Stone, K, Stephens, P, Bendix, J, Woods, T, Carreiro, K, Tran, H, Villa, C, Manson, J
Format:	Journal article
Language:	English
Published:	American Chemical Society 2016

Antiferromagnetism in a family of S = 1 square lattice coordination polymers NiX2(pyz)2 (X = Cl, Br, I, NCS; pyz = Pyrazine).

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