Electronic structures of Pd(II) dimers.

The Pd(II) dimers [(2-phenylpyridine)Pd(mu-X)](2) and [(2-p-tolylpyridine)Pd(mu-X)](2) (X = OAc or TFA) do not exhibit the expected planar geometry (of approximate D(2h) symmetry) but instead resemble an open "clamshell" in which the acetate ligands are perpendicular to the plane containin...

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Autors principals: Bercaw, J, Durrell, A, Gray, H, Green, J, Hazari, N, Labinger, J, Winkler, JR
Format: Journal article
Idioma:English
Publicat: 2010