Silyl Hydrides of Tantalum Supported by Cyclopentadienyl-imido Ligand Sets: Syntheses, X-ray, NMR, and DFT Studies
Reactions of the imido complex Cp(ArN)Ta(PMe 3) 2 (1, Ar = 2,6-diisopropylphenyl) with silanes afford the silyl hydrides Cp(ArN)Ta(PMe 3)(H)(SiR nCl 3-n) (2b-e) and Cp(ArN)Ta(PMe...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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