In-situ electrochemical ESR the oxidation of triphenylacetic acid in acetonitrile

The oxidation of triphenylacetic acid in acetonitrile on platinum electrodes at + 1.94 V (vs. SCE) results in the formation of triphenylmethylcarbonium ions. If the potential is subsequently stepped to values negative of the Φ3C+/Φ3C· standard electrode potential (+0.25 V vs. SCE), reduction to the...

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Autori principali: Compton, R, Coles, B, Day, M
Natura: Journal article
Lingua:English
Pubblicazione: 1986