The chemistry of the 2-Phosphaethynolate anion

In all likelihood the first synthesis of the phosphaethynolate anion, PCO- , was performed in 1894 when NaPH2 was reacted with CO in an attempt to make Na(CP) accompanied by elimination of water. This reaction was repeated 117 years later when it was discovered that Na(OCP) and H2 are the products o...

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Bibliographic Details
Main Authors: Goicoechea, J, Grützmacher, H
Format: Journal article
Language:English
Published: Wiley 2018