Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment.

Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment.

The reaction of (eta(5)-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C-H insertion) to the Cp ring, thereby generating the zwitterion [eta(5)-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield.

Bibliographische Detailangaben
Hauptverfasser: Aldridge, S, Kays, D, Al-Fawaz, A, Jones, K, Horton, P, Hursthouse, M, Harrington, R, Clegg, W
Format: Journal article
Sprache:English
Veröffentlicht: 2006

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