New titanium and zirconium sandwich and half-sandwich complexes containing the C(5)Me(4)CH(2)CH(2)CH=CH2(Cp(=)) ligand
The syntheses and characterization of new titanium and zirconium derivatives of the C5Me4CH2CH2CH=CH2(Cp =) ligand are described. Reaction of LiCp= with ZrCl4 in diethyl ether afforded the half-sandwich derivative [Zr2(η-Cp=)2Cl4(μ-Cl) 2] which is a precursor to the mixed-ring zirconocenes [Zr(η-Cp=...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1996
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