Evaluation of the relative importance of Ti-Cl center dot center dot center dot H-N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl-2(NHMe2)(2)] (R = Pr-i, C6H5 or C6F5)
The three closely-related compounds [Ti-(NiPr)Cl2(NHMe2)2] 1, [Ti(N6H5)Cl2(NHMe2)2] 2 and [Ti(NC6F5)Cl2(NHMe2)2] 3 all crystallize in the space group C2/c with the titanium atoms lying on two-fold axes at (0, y, 1/4); in compounds 1 and 2 the molecules are linked in one-dimensional infinite chains b...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2001
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