Evaluation of the relative importance of Ti-Cl center dot center dot center dot H-N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl-2(NHMe2)(2)] (R = Pr-i, C6H5 or C6F5)
The three closely-related compounds [Ti-(NiPr)Cl2(NHMe2)2] 1, [Ti(N6H5)Cl2(NHMe2)2] 2 and [Ti(NC6F5)Cl2(NHMe2)2] 3 all crystallize in the space group C2/c with the titanium atoms lying on two-fold axes at (0, y, 1/4); in compounds 1 and 2 the molecules are linked in one-dimensional infinite chains b...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2001
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| _version_ | 1797088620071354368 |
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| author | Adams, N Cowley, A Dubberley, SR Sealey, A Skinner, M Mountford, P |
| author_facet | Adams, N Cowley, A Dubberley, SR Sealey, A Skinner, M Mountford, P |
| author_sort | Adams, N |
| collection | OXFORD |
| description | The three closely-related compounds [Ti-(NiPr)Cl2(NHMe2)2] 1, [Ti(N6H5)Cl2(NHMe2)2] 2 and [Ti(NC6F5)Cl2(NHMe2)2] 3 all crystallize in the space group C2/c with the titanium atoms lying on two-fold axes at (0, y, 1/4); in compounds 1 and 2 the molecules are linked in one-dimensional infinite chains by intermolecular Ti-Cl···H-N hydrogen bonds along the direction of the crystallographic c axis, whereas in 3 offset face-to-face interactions between the C6F5 rings break down the hydrogen bonded chains. |
| first_indexed | 2024-03-07T02:52:43Z |
| format | Journal article |
| id | oxford-uuid:ae3a04f4-6ef1-49a2-9cfc-381f246431d8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:52:43Z |
| publishDate | 2001 |
| record_format | dspace |
| spelling | oxford-uuid:ae3a04f4-6ef1-49a2-9cfc-381f246431d82022-03-27T03:41:11ZEvaluation of the relative importance of Ti-Cl center dot center dot center dot H-N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl-2(NHMe2)(2)] (R = Pr-i, C6H5 or C6F5)Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ae3a04f4-6ef1-49a2-9cfc-381f246431d8EnglishSymplectic Elements at Oxford2001Adams, NCowley, ADubberley, SRSealey, ASkinner, MMountford, PThe three closely-related compounds [Ti-(NiPr)Cl2(NHMe2)2] 1, [Ti(N6H5)Cl2(NHMe2)2] 2 and [Ti(NC6F5)Cl2(NHMe2)2] 3 all crystallize in the space group C2/c with the titanium atoms lying on two-fold axes at (0, y, 1/4); in compounds 1 and 2 the molecules are linked in one-dimensional infinite chains by intermolecular Ti-Cl···H-N hydrogen bonds along the direction of the crystallographic c axis, whereas in 3 offset face-to-face interactions between the C6F5 rings break down the hydrogen bonded chains. |
| spellingShingle | Adams, N Cowley, A Dubberley, SR Sealey, A Skinner, M Mountford, P Evaluation of the relative importance of Ti-Cl center dot center dot center dot H-N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl-2(NHMe2)(2)] (R = Pr-i, C6H5 or C6F5) |
| title | Evaluation of the relative importance of Ti-Cl center dot center dot center dot H-N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl-2(NHMe2)(2)] (R = Pr-i, C6H5 or C6F5) |
| title_full | Evaluation of the relative importance of Ti-Cl center dot center dot center dot H-N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl-2(NHMe2)(2)] (R = Pr-i, C6H5 or C6F5) |
| title_fullStr | Evaluation of the relative importance of Ti-Cl center dot center dot center dot H-N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl-2(NHMe2)(2)] (R = Pr-i, C6H5 or C6F5) |
| title_full_unstemmed | Evaluation of the relative importance of Ti-Cl center dot center dot center dot H-N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl-2(NHMe2)(2)] (R = Pr-i, C6H5 or C6F5) |
| title_short | Evaluation of the relative importance of Ti-Cl center dot center dot center dot H-N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl-2(NHMe2)(2)] (R = Pr-i, C6H5 or C6F5) |
| title_sort | evaluation of the relative importance of ti cl center dot center dot center dot h n hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of ti nr cl 2 nhme2 2 r pr i c6h5 or c6f5 |
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