Evaluation of the relative importance of Ti-Cl center dot center dot center dot H-N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl-2(NHMe2)(2)] (R = Pr-i, C6H5 or C6F5)
The three closely-related compounds [Ti-(NiPr)Cl2(NHMe2)2] 1, [Ti(N6H5)Cl2(NHMe2)2] 2 and [Ti(NC6F5)Cl2(NHMe2)2] 3 all crystallize in the space group C2/c with the titanium atoms lying on two-fold axes at (0, y, 1/4); in compounds 1 and 2 the molecules are linked in one-dimensional infinite chains b...
Main Authors: | Adams, N, Cowley, A, Dubberley, SR, Sealey, A, Skinner, M, Mountford, P |
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Format: | Journal article |
Language: | English |
Published: |
2001
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