Salt and isotope effects upon a multistep electrode reaction: the reduction of nitromethane on mercury

The reduction of nitromethane has been studied by impedance voltammetry at various water activities using NaClO4 as the base electrolyte. The impedance analysis conforms well to an EC-C-eee mechanism, and the rate constants for the three rate determining steps are obtained together with the standard...

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Bibliographic Details
Main Authors: Prieto, F, Rueda, M, Compton, R
Format: Journal article
Language:English
Published: Elsevier 1999