Salt and isotope effects upon a multistep electrode reaction: the reduction of nitromethane on mercury
The reduction of nitromethane has been studied by impedance voltammetry at various water activities using NaClO4 as the base electrolyte. The impedance analysis conforms well to an EC-C-eee mechanism, and the rate constants for the three rate determining steps are obtained together with the standard...
Main Authors: | , , |
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Format: | Journal article |
Language: | English |
Published: |
Elsevier
1999
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