Alkyl dehydrogenation in iridium tri-cyclopentyl phosphines
The iridium cyclooctadiene complex incorporating a tricyclopentyl phosphine ligand (PCyp3), Ir(η2:η2-C8H12)(PCyp3)Cl, has been prepared. Removal of the chloride from this complex using Na [BArF4] [ArF = C6 H3 (CF3)2] in CH2Cl2/arene solvent results in dehydrogenation (C-H activation followed by β-H...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Sprog: | English |
| Udgivet: |
2010
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