Redox-dependent conformational switching of diphenylacetylenes

Herein we describe the design and synthesis of a redox-dependent single-molecule switch. Appending a ferrocene unit to a diphenylacetylene scaffold gives a redox-sensitive handle, which undergoes reversible one-electron oxidation, as demonstrated by cyclic voltammetry analysis. <sup>1</sup&...

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Detalhes bibliográficos
Main Authors: Jones, I, Knipe, P, Michaelos, T, Thompson, S, Hamilton, A
Formato: Journal article
Idioma:English
Publicado em: Multidisciplinary Digital Publishing Institute 2014
Assuntos: