Exchange of coordinated solvent during crystallisation of a metal-organic framework observed by in situ high energy X-ray diffraction.

Using time-resolved monochromatic high energy X-ray diffraction, we present an in situ study of the solvothermal crystallisation of a new MOF [Yb2 (BDC)3 (DMF)2 ]⋅H2 O (BDC=benzene-1,4-dicarboxylate and DMF=N,N-dimethylformamide) under solvothermal conditions, from mixed water/DMF solvent. Analysis...

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Bibliographic Details
Main Authors: Wu, Y, Breeze, M, Clarkson, C, Millange, F, O'Hare, D, Walton, R
Format: Journal article
Language:English
Published: Wiley 2016