Theory of optical transitions in curved chromophores

Using first order perturbation theory in the Born-Oppenheimer regime of the Frenkel- Holstein model, we develop a theory for the optical transitions in curved chromophores of π-conjugated polymers. Our key results are that for absorption, A, and emission, I, polarized parallel to the 0 - 0 transitio...

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Detalhes bibliográficos
Main Authors: Barford, W, Marcus, M
Formato: Journal article
Publicado em: AIP Publishing 2016