Synthesis and trifluoromethylation of allylsilanes

Synthesis and trifluoromethylation of allylsilanes

<p>The first part of this thesis presents a novel approach for synthesising enantioenriched cyclic allylsilanes via asymmetric ring-closing metathesis (ARCM). The second part of this thesis focuses on the reactivity of allylsilanes in electrophilic trifluoromethylation under transition metal a...

Deskribapen osoa

Xehetasun bibliografikoak
Egile nagusia:	Galicia Lopez, O
Beste egile batzuk:	Gouverneur, V
Formatua:	Thesis
Hizkuntza:	English
Argitaratua:	2013
Gaiak:	Organic synthesis Catalysis

Antzeko izenburuak

Trifluoromethylation of allylsilanes under copper catalysis.
nork: Mizuta, S, et al.
Argitaratua: (2012)

Trifluoromethylation of allylsilanes under photoredox catalysis.
nork: Mizuta, S, et al.
Argitaratua: (2013)

Direct Synthesis of Bicyclic Acetals via Visible Light Catalysis
nork: Fengjin Wu, et al.
Argitaratua: (2020-08-01)

Convenient One-Pot Synthesis of Allylsilanes from Enolizable Ketones
nork: Man Lung D. Kwan, et al.
Argitaratua: (2019-10-01)

Synthesis of α-tertiary allylsilanes by palladium-catalyzed hydrosilylation of 1,1-disubstituted allenes
nork: Kaidi Li, et al.
Argitaratua: (2020-11-01)

Direct fluorination : a new method for the synthesis of trifluoromethyl compounds.
nork: Liu, Edmund Kin Sing
Argitaratua: (2005)

Asymmetric organocatalysis : from biomimetic concepts to applications in asymmetric synthesis /
nork: 398273 Berkessel, Albrecht, et al.
Argitaratua: (2005)

Direct synthesis of p-methyl benzaldehyde from acetaldehyde via an organic amine-catalyzed dehydrogenation mechanism
nork: Qing-Nan Wang, et al.
Argitaratua: (2021-09-01)

Nickel-Catalyzed, One-Pot Synthesis of Pyrazoles
nork: Nassima Medjahed, et al.
Argitaratua: (2022-11-01)

The development of nitro-Mannich/hydroamination cascades for the synthesis of substituted N-heterocycles
nork: Barber, D, et al.
Argitaratua: (2013)

Development of catalytic methods to exploit sulfur dioxide in organic synthesis
nork: Emmett, EJ
Argitaratua: (2014)

Copper-catalyzed radical trans-selective hydroboration of ynamides with N-heterocyclic carbene boranes
nork: Kefeng Wang, et al.
Argitaratua: (2022-09-01)

Proton Transfer Can Govern Regioselectivity Assisted by Iron Catalysis
nork: Yudong Li, et al.
Argitaratua: (2020-06-01)

New reactivity and selectivity in rhodium-catalysed hydroacylation
nork: Pal, R
Argitaratua: (2020)

Exploiting sulfinate coupling partners for the preparation of diversely functionalised heterocycles
nork: McKnight, J
Argitaratua: (2022)

Alcohol imination catalyzed by carbon nanostructures synthesized by C(sp2)-C(sp3) free radical coupling
nork: Cheng Wang, et al.
Argitaratua: (2023-05-01)

Diastereocontrolled synthesis of hetero- and carbocycles via manganese(III) and copper(II): towards a novel prostaglandin total synthesis
nork: Docherty, P, et al.
Argitaratua: (2008)

Palladium-catalysed cyclisations of bromoenynamides in the synthesis and applications of amidodienes
nork: Greenaway, R
Argitaratua: (2013)

Synthesis of new triazole-based trifluoromethyl scaffolds
nork: Michela Martinelli, et al.
Argitaratua: (2008-05-01)

Catalytic asymmetric synthesis /
nork: Ojima, Iwao, 1945-
Argitaratua: (2000)

Catalytic asymmetric synthesis /
nork: Ojima, Iwao, 1945-
Argitaratua: (c201)

Catalysis in asymmetric synthesis /
nork: 235653 Caprio, Vittorio, et al.
Argitaratua: (2009)

Catalytic asymmetric synthesis /
nork: Ojima Iwao
Argitaratua: (1993)

Recent Applications of TEMPO in Organic Synthesis and Catalysis
nork: Ravi Varala, et al.
Argitaratua: (2023-09-01)

SYNERGISMS BETWEEN METAL AND PHOTOREDOX CATALYSIS: DECONVOLUTING COMPLEX SYSTEMS
nork: Alessandra A. G. Fernandes, et al.
Argitaratua: (2020-08-01)

Asymmetric catalysis in organic synthesis /
nork: 196323 Noyori, Ryoji
Argitaratua: (1994)

Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagent
nork: Xiao-Ping Wang, et al.
Argitaratua: (2013-11-01)

Enantioselective synthesis and reactivity of benzylic fluorides
nork: Blessley, G, et al.
Argitaratua: (2013)

Cyclisation cascades via reactive iminium intermediates
nork: Gregory, AW
Argitaratua: (2014)

Catalytic asymmetric carbon-carbon bond formation using alkenes as alkylmetal equivalents
nork: Maksymowicz, R
Argitaratua: (2014)

Studies towards the nucleophilic dearomatisation of electron-deficient heteroaromatics and hydrogen borrowing reactions of methanol
nork: Poole, DL
Argitaratua: (2014)

Special Issue: “Advances in Homogeneous Catalysis”
nork: Joaquín García-Álvarez
Argitaratua: (2020-03-01)

Palladium-catalysed enolate arylation in the synthesis of isoquinolines
nork: Gatland, A, et al.
Argitaratua: (2014)

Copper Sulfate (CuSO<sub>4</sub>): An Efficient Reagent in Organic Synthesis
nork: Housemberg D. S. Ferrreira, et al.
Argitaratua: (2023-08-01)

Application of Microwave in Organic Synthesis. Dry Synthesis of 2-Arylmethylene-3(2)-naphthofuranones
nork: Nathalie Bar, et al.
Argitaratua: (1998-03-01)

Catalytic asymmetric conjugate addition of mercaptans to β-substituted-β-trifluoromethyl oxazolidinone enoates : access to chiral trifluoromethylated tertiary thioethers and thiols
nork: Chen, Wenchao, et al.
Argitaratua: (2014)

Copper-Catalyzed Trifluoromethylation of Alkoxypyridine Derivatives
nork: Nandor Gyorfi, et al.
Argitaratua: (2020-10-01)

Towards the synthesis of anthecularin and anthecotulides
nork: Talbot, E
Argitaratua: (2011)

Highly Reactive Cyclic Monoaryl Iodoniums Tuned as Carbene Generators Couple with Nucleophiles under Metal-Free Conditions
nork: Haiwen Wang, et al.
Argitaratua: (2020-07-01)

Hydrogen borrowing reactions of amino alcohols and the total synthesis of (–)-γ-lycorane
nork: Hall, C
Argitaratua: (2021)