Cation exchange in a 3D perovskite-synthesis of Ni(0.5)TaO₃.
Reaction of NiCl2 with NaTaO3 leads the formation of the perovskite phase Ni(0.5)TaO3, via a topochemical nickel-for-sodium cation exchange in which the framework of apex-linked TaO6 octahedra present in the parent phase is retained. Neutron powder diffraction data indicate Ni(0.5)TaO3 adopts a stru...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2014
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