Cation exchange in a 3D perovskite-synthesis of Ni(0.5)TaO₃.

Reaction of NiCl2 with NaTaO3 leads the formation of the perovskite phase Ni(0.5)TaO3, via a topochemical nickel-for-sodium cation exchange in which the framework of apex-linked TaO6 octahedra present in the parent phase is retained. Neutron powder diffraction data indicate Ni(0.5)TaO3 adopts a stru...

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Main Authors: Amano Patino, M, Smith, T, Zhang, W, Halasyamani, P, Hayward, M
格式: Journal article
语言:English
出版: American Chemical Society 2014

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