Roaming is the dominant mechanism for molecular products in acetaldehyde photodissociation.
Reaction pathways that bypass the conventional saddle-point transition state (TS) are of considerable interest and importance. An example of such a pathway, termed "roaming," has been described in the photodissociation of H(2)CO. In a combined experimental and theoretical study, we show th...
| Autori principali: | , , , , , , , |
|---|---|
| Natura: | Journal article |
| Lingua: | English |
| Pubblicazione: |
2008
|