Roaming is the dominant mechanism for molecular products in acetaldehyde photodissociation.

Reaction pathways that bypass the conventional saddle-point transition state (TS) are of considerable interest and importance. An example of such a pathway, termed "roaming," has been described in the photodissociation of H(2)CO. In a combined experimental and theoretical study, we show th...

詳細記述

書誌詳細
主要な著者: Heazlewood, B, Jordan, M, Kable, S, Selby, T, Osborn, D, Shepler, B, Braams, B, Bowman, J
フォーマット: Journal article
言語:English
出版事項: 2008