Contrasting nonclassical silicon-hydrogen interactions in niobium and tantalum half-sandwich complexes: Si-H center dot center dot center dot M agostic versus M-H center dot center dot center dot Si-Cl interligand hypervalent interactions
Reaction of [CpM(NAr)(PMe3)2] (M = Nb, Ta; Ar = 2,6-C6H3iPr2) with HSiClMe2 gives two remarkably different nonclassical Si···H···M products depending only on the identity of M; [CpTa(NAr)(H)(SiMe2Cl)(PMe3)] possesses an unusual electron-rich M-H···Si interligand hypervalent interaction while [CpNb{η...
Những tác giả chính: | Nikonov, G, Mountford, P, Green, J, Cooke, P, Leech, M, Blake, A, Howard, J, Lemenovskii, D |
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Định dạng: | Journal article |
Ngôn ngữ: | English |
Được phát hành: |
2000
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