Fusion and planarization of a quinoidal porphyrin dimer.

The crystal structure, near-infrared spectrum and electrochemistry of a quinoidal triply-linked porphyrin dimer are compared with those of its singly-linked precursor; fusing the two porphyrins planarizes the pi-system and reduces the optical HOMO-LUMO gap while increasing the gap between the first...

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Detalhes bibliográficos
Principais autores: Blake, I, Krivokapic, A, Katterle, M, Anderson, H
Formato: Journal article
Idioma:English
Publicado em: 2002