Fusion and planarization of a quinoidal porphyrin dimer.
The crystal structure, near-infrared spectrum and electrochemistry of a quinoidal triply-linked porphyrin dimer are compared with those of its singly-linked precursor; fusing the two porphyrins planarizes the pi-system and reduces the optical HOMO-LUMO gap while increasing the gap between the first...
| Главные авторы: | , , , |
|---|---|
| Формат: | Journal article |
| Язык: | English |
| Опубликовано: |
2002
|
| _version_ | 1826291931500511232 |
|---|---|
| author | Blake, I Krivokapic, A Katterle, M Anderson, H |
| author_facet | Blake, I Krivokapic, A Katterle, M Anderson, H |
| author_sort | Blake, I |
| collection | OXFORD |
| description | The crystal structure, near-infrared spectrum and electrochemistry of a quinoidal triply-linked porphyrin dimer are compared with those of its singly-linked precursor; fusing the two porphyrins planarizes the pi-system and reduces the optical HOMO-LUMO gap while increasing the gap between the first oxidation and reduction potentials. |
| first_indexed | 2024-03-07T03:06:55Z |
| format | Journal article |
| id | oxford-uuid:b2dcb75f-5f27-44f0-aaa8-b35e2dbaede0 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T03:06:55Z |
| publishDate | 2002 |
| record_format | dspace |
| spelling | oxford-uuid:b2dcb75f-5f27-44f0-aaa8-b35e2dbaede02022-03-27T04:14:40ZFusion and planarization of a quinoidal porphyrin dimer.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:b2dcb75f-5f27-44f0-aaa8-b35e2dbaede0EnglishSymplectic Elements at Oxford2002Blake, IKrivokapic, AKatterle, MAnderson, HThe crystal structure, near-infrared spectrum and electrochemistry of a quinoidal triply-linked porphyrin dimer are compared with those of its singly-linked precursor; fusing the two porphyrins planarizes the pi-system and reduces the optical HOMO-LUMO gap while increasing the gap between the first oxidation and reduction potentials. |
| spellingShingle | Blake, I Krivokapic, A Katterle, M Anderson, H Fusion and planarization of a quinoidal porphyrin dimer. |
| title | Fusion and planarization of a quinoidal porphyrin dimer. |
| title_full | Fusion and planarization of a quinoidal porphyrin dimer. |
| title_fullStr | Fusion and planarization of a quinoidal porphyrin dimer. |
| title_full_unstemmed | Fusion and planarization of a quinoidal porphyrin dimer. |
| title_short | Fusion and planarization of a quinoidal porphyrin dimer. |
| title_sort | fusion and planarization of a quinoidal porphyrin dimer |
| work_keys_str_mv | AT blakei fusionandplanarizationofaquinoidalporphyrindimer AT krivokapica fusionandplanarizationofaquinoidalporphyrindimer AT katterlem fusionandplanarizationofaquinoidalporphyrindimer AT andersonh fusionandplanarizationofaquinoidalporphyrindimer |