Fusion and planarization of a quinoidal porphyrin dimer.

Fusion and planarization of a quinoidal porphyrin dimer.

The crystal structure, near-infrared spectrum and electrochemistry of a quinoidal triply-linked porphyrin dimer are compared with those of its singly-linked precursor; fusing the two porphyrins planarizes the pi-system and reduces the optical HOMO-LUMO gap while increasing the gap between the first...

Bibliográfalaš dieđut
Váldodahkkit:	Blake, I, Krivokapic, A, Katterle, M, Anderson, H
Materiálatiipa:	Journal article
Giella:	English
Almmustuhtton:	2002

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Synthesis and Crystal Structure of a Cumulenic Quinoidal Porphyrin Dimer with Strong Electronic Absorption in the Infrared We thank the Engineering and Physical Sciences Research Council (UK) and the Defence Evaluation and Research Agency (DERA, UK) for support and the EPSRC Mass Spectrometry Service in Swansea for FAB mass spectra.
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