Fusion and planarization of a quinoidal porphyrin dimer.
The crystal structure, near-infrared spectrum and electrochemistry of a quinoidal triply-linked porphyrin dimer are compared with those of its singly-linked precursor; fusing the two porphyrins planarizes the pi-system and reduces the optical HOMO-LUMO gap while increasing the gap between the first...
Huvudupphovsmän: | Blake, I, Krivokapic, A, Katterle, M, Anderson, H |
---|---|
Materialtyp: | Journal article |
Språk: | English |
Publicerad: |
2002
|
Liknande verk
-
Push–pull quinoidal porphyrins
av: Smith, M, et al.
Publicerad: (2018) -
Conjugated quinoidal porphyrin oligomers.
av: Anderson, H, et al.
Publicerad: (2001) -
Synthesis and crystal structure of a cumulenic quinoidal porphyrin dimer with strong electronic absorption in the infrared
av: Blake, I, et al.
Publicerad: (2000) -
Reverse saturable absorption in the near-infrared by fused porphyrin dimers
av: McEwan, K, et al.
Publicerad: (2004) -
Control of electron transfer in a conjugated porphyrin dimer by selective excitation of planar and perpendicular conformers.
av: Winters, M, et al.
Publicerad: (2007)